You can scan all your pages successively in 1 scanning process. Once all your pages have been scanned and are loaded in Paperscan, click: "Save > Save all pages in the same multipage file". The select the format you want to save your document as and click "save" in the bottom right of the window.
If you mean you want to place 16 pages and fit them onto 1 brand new page then this isn't possible unless you manually do this yourself. First you want to save your 16 pages individually. Then get any background and import it to Paperscan. Then you can use this option "Annotations > Image" to import one of your pages 1 by 1 and place them onto your freshly imported background. You do this for all 16 pages by using the "image" feature to draw your chosen page onto your background.
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